A highly active and site selective indium catalyst for lactide polymerization.
Identifieur interne : 000912 ( Main/Exploration ); précédent : 000911; suivant : 000913A highly active and site selective indium catalyst for lactide polymerization.
Auteurs : RBID : pubmed:22729290Abstract
Chiral indium salen complexes are highly active, isoselective catalysts for the ring opening polymerization of racemic lactide. The polymerizations are well controlled and polymers with high molecular weights and low molecular weight distributions are obtained. Preliminary kinetic investigations with the enantiopure complex confirm enantiomorphic site control as the dominant contributor to selectivity and formation of block copolymers.
DOI: 10.1039/c2cc33519k
PubMed: 22729290
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">A highly active and site selective indium catalyst for lactide polymerization.</title><author><name sortKey="Aluthge, Dinesh C" uniqKey="Aluthge D">Dinesh C Aluthge</name><affiliation wicri:level="1"><nlm:affiliation>University of British Columbia, Department of Chemistry, 2036 Main Mall, Vancouver, B.C., Canada.</nlm:affiliation><country xml:lang="fr">Canada</country><wicri:regionArea>University of British Columbia, Department of Chemistry, 2036 Main Mall, Vancouver, B.C.</wicri:regionArea></affiliation></author><author><name sortKey="Patrick, Brian O" uniqKey="Patrick B">Brian O Patrick</name></author><author><name sortKey="Mehrkhodavandi, Parisa" uniqKey="Mehrkhodavandi P">Parisa Mehrkhodavandi</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1039/c2cc33519k</idno><idno type="RBID">pubmed:22729290</idno><idno type="pmid">22729290</idno><idno type="wicri:Area/Main/Corpus">000C32</idno><idno type="wicri:Area/Main/Curation">000C32</idno><idno type="wicri:Area/Main/Exploration">000912</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Chiral indium salen complexes are highly active, isoselective catalysts for the ring opening polymerization of racemic lactide. The polymerizations are well controlled and polymers with high molecular weights and low molecular weight distributions are obtained. Preliminary kinetic investigations with the enantiopure complex confirm enantiomorphic site control as the dominant contributor to selectivity and formation of block copolymers.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">22729290</PMID><DateCreated><Year>2013</Year><Month>04</Month><Day>22</Day></DateCreated><DateCompleted><Year>2013</Year><Month>10</Month><Day>23</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1364-548X</ISSN><JournalIssue CitedMedium="Internet"><Volume>49</Volume><Issue>39</Issue><PubDate><Year>2013</Year><Month>May</Month><Day>14</Day></PubDate></JournalIssue><Title>Chemical communications (Cambridge, England)</Title><ISOAbbreviation>Chem. Commun. (Camb.)</ISOAbbreviation></Journal><ArticleTitle>A highly active and site selective indium catalyst for lactide polymerization.</ArticleTitle><Pagination><MedlinePgn>4295-7</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/c2cc33519k</ELocationID><Abstract><AbstractText>Chiral indium salen complexes are highly active, isoselective catalysts for the ring opening polymerization of racemic lactide. The polymerizations are well controlled and polymers with high molecular weights and low molecular weight distributions are obtained. Preliminary kinetic investigations with the enantiopure complex confirm enantiomorphic site control as the dominant contributor to selectivity and formation of block copolymers.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Aluthge</LastName><ForeName>Dinesh C</ForeName><Initials>DC</Initials><Affiliation>University of British Columbia, Department of Chemistry, 2036 Main Mall, Vancouver, B.C., Canada.</Affiliation></Author><Author ValidYN="Y"><LastName>Patrick</LastName><ForeName>Brian O</ForeName><Initials>BO</Initials></Author><Author ValidYN="Y"><LastName>Mehrkhodavandi</LastName><ForeName>Parisa</ForeName><Initials>P</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Chem Commun (Camb)</MedlineTA><NlmUniqueID>9610838</NlmUniqueID><ISSNLinking>1359-7345</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>6</Month><Day>26</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>6</Month><Day>26</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>6</Month><Day>26</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1039/c2cc33519k</ArticleId><ArticleId IdType="pubmed">22729290</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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